1.6: Functional Groups (2025)

Table of Contents

Learning Outcomes Alkanes Alkenes and alkynes Aromatics Haloalkanes Alcohols, phenols, and thiols Ethers and sulfides Amines Organic phosphates Aldehydes, ketones, and imines Carboxylic acid derivatives Nitriles EXERCISE 1.12 Exercise 1.13 Further Reading FAQs

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Learning Outcomes

Describe the importance and purpose of functional groups in organic reactions.
Identify and name functional groups in compounds.

With over twenty million known organic compounds in existence, it would be very challenging to memorize chemical reactions for each one. Fortunately, molecules with similar functional groups tend to undergo similar reactions. Functional groups are structural units within organic compounds that are defined by specific bonding arrangements between specific atoms. For example the structure of capsaicin, found in chili peppers, incorporates several functional groups, labeled in the figure below and explained throughout this section.

Even if other parts of the molecule are quite different, certain functional groups tend to react in certain ways. As we progress in our study of organic chemistry, it will become extremely important to be able to quickly recognize the most common functional groups, because they are the key structural elements that define how organic molecules react. For now, we will only worry about drawing and recognizing each functional group, as depicted by Lewis and line structures. Much of the remainder of your study of organic chemistry will be taken up with learning about how the different functional groups behave in organic reactions.

The ‘default’ in organic chemistry (essentially, the lack of any functional groups) is given the term alkane, characterized by single bonds between carbon and carbon, or between carbon and hydrogen. Methane, CH₄, is the natural gas you may burn in your furnace. Octane, C₈H₁₈, is a component of gasoline.

Alkanes

Alkenes (sometimes called olefins) have carbon-carbon double bonds, and alkynes have carbon-carbon triple bonds. Ethene, the simplest alkene example, is a gas that serves as a cellular signal in fruits to stimulate ripening. (If you want bananas to ripen quickly, put them in a paper bag along with an apple – the apple emits ethene gas, setting off the ripening process in the bananas). Ethyne, commonly called acetylene, is used as a fuel in welding blow torches.

Alkenes and alkynes

Later, we will study the nature of the bonding on alkenes and alkynes, and learn that that the bonding in alkenes is trigonal planar in in alkynes is linear. Furthermore, many alkenes can take two geometric forms: cis or trans. The cis and trans forms of a given alkene are different molecules with different physical properties because, as we will learn in chapter 2, there is a very high energy barrier to rotation about a double bond. In the example below, the difference between cis and trans alkenes is readily apparent.

We will have more to say about the subject of cis and trans alkenes in chapter 3, and we will learn much more about the reactivity of alkenes in chapter 10.

Alkanes, alkenes, and alkynes are all classified as hydrocarbons, because they are composed solely of carbon and hydrogen atoms. Alkanes are said to be saturated hydrocarbons, because the carbons are bonded to the maximum possible number of hydrogens – in other words, they are saturated with hydrogen atoms. The double and triple-bonded carbons in alkenes and alkynes have fewer hydrogen atoms bonded to them – they are thus referred to as unsaturated hydrocarbons.

The aromatic group is exemplified by benzene (which used to be a commonly used solvent in the organic lab, but which was shown to be carcinogenic), and naphthalene, a compound with a distinctive ‘mothball’ smell. Aromatic groups are planar (flat) ring structures, and are widespread in nature. We will learn more about the structure and reactions of aromatic groups next semester.

Aromatics

When the carbon of an alkane is bonded to one or more halogens, the group is referred to as a alkyl halide or haloalkane. Chloroform is a useful solvent in the laboratory, and was one of the earlier anesthetic drugs used in surgery. Chlorodifluoromethane was used as a refrigerant and in aerosol sprays until the late twentieth century, but its use was discontinued after it was found to have harmful effects on the ozone layer. Bromoethane is a simple alkyl halide often used in organic synthesis. Alkyl halides groups are quite rare in biomolecules.

Haloalkanes

In the alcohol functional group, a carbon is single-bonded to an OH group (the OH group, by itself, is referred to as a hydroxyl). Except for methanol, all alcohols can be classified as primary, secondary, or tertiary. In a primary alcohol, the carbon bonded to the OH group is also bonded to only one other carbon. In a secondary alcohol and tertiary alcohol, the carbon is bonded to two or three other carbons, respectively. When the hydroxyl group is directly attached to an aromatic ring, the resulting group is called a phenol. The sulfur analog of an alcohol is called a thiol (from the Greek thio, for sulfur).

Alcohols, phenols, and thiols

Note that the definition of a phenol states that the hydroxyl oxygen must be directly attached to one of the carbons of the aromatic ring. The compound below, therefore, is not a phenol – it is a primary alcohol.

The distinction is important, because as we will see later, there is a significant difference in the reactivity of alcohols and phenols.

We are already familiar with several common alcohols. For example, ethanol $$\left( \ce{CH_3CH_2OH} \right)$$ is the alcohol present in alcoholic beverages. It is also widely used in the industrial manufacture of other chemicals. Methanol $$\left( \ce{CH_3OH} \right)$$ is used as a gasoline additive or alternative. Additionally, methanol can be used to manufacture formaldehyde, which is employed in the production of plastics, paints, and other useful substances. Isopropanol is commonly known as rubbing alcohol. In addition to its industrial uses, isopropanol is used to clean various surfaces, including computer monitors, whiteboards, and even skin (e.g., before getting blood drawn).

The deprotonated forms of alcohols, phenols, and thiols are called alkoxides, phenolates, and thiolates, respectively. A protonated alcohol is an oxonium ion.

In an ether functional group, a central oxygen is bonded to two carbons. Below is the structure of diethyl ether, a common laboratory solvent and also one of the first compounds to be used as an anesthetic during operations. Ethers are good solvents for other organic compounds because of their low reactivity. They readily dissolve nonpolar molecules. The sulfur analog of an ether is called a thioether or sulfide.

Ethers and sulfides

Amines are characterized by nitrogen atoms with single bonds to hydrogen and carbon. Just as there are primary, secondary, and tertiary alcohols, there are primary, secondary, and tertiary amines. Ammonia is a special case with no carbon atoms.

One of the most important properties of amines is that they are basic, and are readily protonated to form ammonium cations. In the case where a nitrogen has four bonds to carbon (which is somewhat unusual in biomolecules), it is called a quaternary ammonium ion.

Many smaller amines have very strong and offensive odors. For example, the aptly-named compounds cadaverine and putrescine are foul-smelling amines, formed as a part of the decay process after death.

Amines serve a wide variety of uses. Diphenylamineacts as a stabilizer for certain types of explosives. Amines are found as components in some lubricating materials, in developers, and are a part of waterproofing textiles. Some amines, such as novocaine, are used as anesthetics. Many pharmaceutical compounds contain amines, including 8 of the 10 most prescribed medications in 2012.

Amines

Note: Do not be confused by how the terms ‘primary’, ‘secondary’, and ‘tertiary’ are applied to alcohols and amines – the definitions are different. In alcohols, what matters is how many other carbons the alcohol carbon is bonded to, while in amines, what matters is how many carbons the nitrogen is bonded to.

Phosphate and its derivative functional groups are ubiquitous in biomolecules. Phosphate linked to a single organic group is called a phosphate ester; when it has two links to organic groups it is called a phosphate diester. A linkage between two phosphates creates a phosphate anhydride.

Organic phosphates

There are a number of functional groups that contain a carbon-oxygen double bond, which is commonly referred to as a carbonyl. Ketones and aldehydes are two closely related carbonyl-based functional groups that react in very similar ways. In a ketone, the carbon atom of a carbonyl is bonded to two other carbons. In an aldehyde, the carbonyl carbon is bonded on one side to a hydrogen, and on the other side to a carbon. The exception to this definition is formaldehyde, in which the carbonyl carbon has bonds to two hydrogens.

The simplest aldehyde has a carbonyl group bonded to two hydrogen atoms. This molecule, called formaldehyde, can be used as a tissue preservative or as a very harsh disinfectant. It is also used as a precursor to various materials, including plastics, resins, and other polymers.

Ketones undergo most of the same reactions as aldehydes, but they tend to be slightly less reactive. The simplest ketone is acetone, in which the carbonyl carbon is bonded to two $$\ce{CH_3}$$ groups. This ketone is commonly used to remove fingernail polish and serves as an industrial solvent. Methyl ethyl ketone is used as a paint stripper and a solvent. Ketones are also used in the production of various polymers, either as a building block or as a solvent.

A group with a carbon-nitrogen double bond is called an imine, or sometimes a Schiff base (in this book we will use the term ‘imine’).

Aldehydes, ketones, and imines

When a carbonyl carbon is bonded on one side to a carbon (or hydrogen) and on the other side to an oxygen, nitrogen, or sulfur, the functional group is considered to be one of the ‘carboxylic acid derivatives’, a designation that describes a set of related functional groups. The eponymous member of this family is the carboxylic acid functional group, in which the carbonyl is bonded to a hydroxyl group. The conjugate base of a carboxylic acid is a carboxylate.

As the name implies, carboxylic acids are weak acids. An $$\ce{OH}$$ group that is directly connected to a carbonyl will ionize to a small extent when dissolved in water. because of the relative stability of the resulting anion. A carboxylate ion (see figure below), in which the negative charge is spread over two different oxygen atoms through resonance structures, is more stable than an isolated oxygen-centered anion.

Carboxylic acids are used in a variety of environments. Formic acid acts as a protective chemical for many stinging insects and plants. Acetic acid gives vinegar its characteristic smell and flavor and is a fundamental biological and industrial building block. Carboxylic acids with longer carbon chains (fatty acids) are used by animals as a way of storing energy and are widely used in the manufacture of soaps. Some compounds contain multiple carboxylic acids within a single molecule. For example, citric acid (three carboxyl groups) is especially abundant in citrus fruits and it used as a flavoring and preservative in many foods and beverages.

Other derivatives are carboxylic esters (usually just called ‘esters’), thioesters, amides, acyl phosphates, acid chlorides, and acid anhydrides. With the exception of acid chlorides and acid anhydrides, the carboxylic acid derivatives are very common in biological molecules and/or metabolic pathways.

Esters are very important in synthesis and in nature. Some esters have very pleasant odors, so they are used in the manufacture of many perfumes. Propyl acetate contributes to the odor of pears, while isoamyl acetate gives bananas their smell. This ester also serves as an alarm signal for honeybees. Esters are employed in the manufacture of fabrics (polyesters) and Plexiglass. Anesthetics such as procaine and benzocaine also contain esters.

The amide group forms is extremely important in biological systems, where it is called a “peptide”, used for linking amino acids together to form polypeptides and (ultimately) proteins. Amides are used as coloring agents in crayons, pencils, and ink. They are employed in the paper, plastic, and rubber industries. Polyacrylamide is a very widely used amide; it is involved in t he treatment of drinking water and sewage, and in plastics manufacture. The amide Kevlar is widely employed for the production of body armor, and nylon is another type of amide-based polymer.

Carboxylic acid derivatives

Finally, a nitrile group is characterized by a carbon triple-bonded to a nitrogen.

Nitriles

A single compound often contains several functional groups, particularly in biological organic chemistry. The six-carbon sugar molecules glucose and fructose, for example, contain aldehyde and ketone groups, respectively, and both contain five alcohol groups (a compound with several alcohol groups is often referred to as a ‘polyol’).

The hormone testosterone, the amino acid phenylalanine, and the glycolysis metabolite dihydroxyacetone phosphate all contain multiple functional groups, as labeled below.

While not in any way a complete list, this section has covered most of the important functional groups that we will encounter in synthetic and biological organic chemistry. A summary table is included in your workbook, and is reproduced here for reference; the “priority” is used when determining how to name a compound with multiple functional groups. We will formally learn how to name functional groups later.

Priority order for functional groups in IUPAC nomenclature

Functional Group Family	Functional Group Structure	Name if main group	Name if substituent
Carboxylic acid		alkanoic acid	carboxy
Ester		alkyl alkanoate	alkoxycarbonyl
Amide		alkanamide	amido
Nitrile		alkanenitrile	cyano
Aldehyde		alkanal	formyl
Ketone		alkanone	oxo
Alcohol		alkanol	hydroxy
Amine		alkanamine	amino
Alkene		alkene	alkenyl
Alkyne		alkyne	alkynyl
Alkane		alkane	alkyl
Ether			alkoxy
Halide			halo
Nitro compound			nitro

EXERCISE 1.12

Identify the functional groups (other than alkanes) in the following organic compounds. State whether alcohols and amines are primary, secondary, or tertiary.

Solutions to exercises

[reveal-answer q=”628316″]Show Solution[/reveal-answer]
[hidden-answer a=”628316″]

a) carboxylate, sulfide, aromatic, two amide groups (one of which is cyclic)

b) tertiary alcohol, thioester

c) carboxylate, ketone

d) ether, primary amine, alkene

[/hidden-answer]

Exercise 1.13

Draw one example each of compounds fitting the descriptions below, using line structures. Be sure to designate the location of all non-zero formal charges. All atoms should have complete octets (phosphorus may exceed the octet rule). There are many possible correct answers for these, so be sure to check your structures with your instructor or tutor.

a) a compound with molecular formula C₆H₁₁NO that includes alkene, secondary amine, and primary alcohol functional groups

b) an ion with molecular formula C₃H₅O₆P ^2- that includes aldehyde, secondary alcohol, and phosphate functional groups.

c) A compound with molecular formula C₆H₉NO that has an amide functional group, and does not have an alkene group.

Khan Academy video tutorial on functional groups:

A YouTube element has been excluded from this version of the text. You can view it online here: http://pb.libretexts.org/ochem1walker/?p=33

FAQs

What functional group is the easiest? ›

The simplest functional group in organic chemistry (which is often ignored when listing functional groups) is called an alkane, characterized by single bonds between two carbons and between carbon and hydrogen.

How can I learn functional groups easily? ›

Students can easily memorize the functional groups by using mnemonics. Following are some common mnemonics for functional groups: Vowels: The vowels "A", "E", and "Y" before the last two words “ne” of any alkyl group represent alkane, alkene, and alkyne, respectively.

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What is the priority order trick for functional groups? ›

Final answer: Yes, there is a trick to memorize the priority order of functional groups in IUPAC naming. You can use the mnemonic 'CARBOHOPSN' which stands for Carboxylic acid, Acid anhydride, Ester, Amide, Alcohol, Aldehyde, Ketone, Ether, Amine, Halide, and Nitrile.

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What are the 7 main functional groups? ›

Some of the important functional groups in biological molecules include: hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl groups. These groups play an important role in the formation of molecules like DNA, proteins, carbohydrates, and lipids.

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What is the strongest functional group? ›

As a rule of thumb, the higher the oxidation state of the central carbon, the higher the priority of the functional group. Thus, carboxylic acids have higher priority than alcohols, and so on (See also table 21-1 in your textbook). 1. CARBOXYLIC ACIDS (highest priority among carbon-containing functional groups).

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What are functional groups for dummies? ›

A functional group is defined as an atom or group of atoms within a molecule that has similar chemical properties whenever it appears in various compounds. Even if other parts of the molecule are quite different, certain functional groups tend to react in certain ways.

Should I memorize the functional groups? ›

The answer is simple: If you can't master remembering functional groups, you're going to miss out on the future in organic chemistry you deserve.

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What are the most basic functional groups? ›

Common functional groups in biology

Functional Group	Properties
Hydroxyl	Polar
Methyl	Nonpolar
Carbonyl	Polar
Carboxyl	Charged (forms R-COO ‍ ) at the pH of most biological systems. Since carboxyl groups can release H ‍ into solution, they are considered acidic.

3 more rows

Why is it important to study functional groups? ›

Functional groups are important in chemistry because they are the portion of a molecule that is capable of characteristic reactions. They, therefore, determine the properties and chemistry of many organic compounds.

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How many functional groups are there? ›

Common examples of functional groups are alcohols, alkenes, alkynes, amines, carboxylic acids, aldehydes, ketones, esters, and ethers, among others. In a typical sophomore organic chemistry course, there are about 15 key functional groups, with another group of 10 or so that make consistent appearances.

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How to remember ether vs ester? ›

The main difference between ether and ester lies in their structure. An ester group requires two oxygen atoms and two carbon atoms to complete its characteristic structure, while an ether group only needs one oxygen atom and two carbon atoms for its structure.

Do functional groups take priority in naming? ›

This priority order is important in nomenclature as the higher priority group is the principle functional group and it is typically numbered such that is has the lowest number (the locant). You need to learn to recognise these functional groups not just for nomenclature but in order to recognise their reactions later.

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What is the easiest way to learn functional groups? ›

One of the easiest ways to learn functional groups is by making flash cards. Get a pack of index cards and write the name of the functional group on one side, and draw its chemical representation on the other. For now, a list of the most important ones you should know is provided here.

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What does R stand for in functional groups? ›

Functional groups are involved in naming organic compounds. R is the general abbreviation for the "rest of the molecule".

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How to identify a functional group? ›

Functional groups will have different prefixes from their suffixes to distinguish them within the name. For example the amine functional group will use "-amine" as the suffix is it the highest priority group, but use the "amino-" prefix if it is the lower priority group as is a substituent. Hope that helps.

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Which functional group is preferred? ›

According to the priority table preference of given functional groups is: anhydride > aldehydes > ketone > alcohols > alkenes.

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Which functional group is more basic? ›

The functional group that behaves as a base is the amino group (-NH₂). In organic chemistry, a functional group is a group of atoms that gives a molecule its characteristic chemical and physical properties. The amino group is a common functional group that contains a nitrogen atom bonded to two hydrogen atoms.

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What is the easiest functional programming language? ›

### What is the easiest functional programming language? Elm is often seen as one of the easiest languages for beginners. It is inspired by Haskell but is simpler and compiles to JavaScript. Elm is straightforward, making it a good choice for starting to build web apps.

Which functional group has least priority? ›

Alkenes And Alkynes

If carbon-carbon multiple bonds are present in the molecule, they are considered as substituents with a priority (or “seniority”, according to IUPAC) lower than that of amines. So for a molecule with an alkene and an alcohol, the alcohol has priority and the molecule has the suffix, “-ol”.

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